Menthone Glycerin Acetal
Menthone Glycerin Acetal (D,L-Menthone 1,2-glycerol ketal), also known as menthone glycerol ketal, is a clear, colourless viscous liquid with a slight minty aroma that is almost imperceptible on the tongue but delivers a lingering, pleasant cooling effect. Available in both racemic and levorotatory specifications—with the levorotatory form predominant in commercial offerings—it is synthesised as a cooling agent through the acid-catalysed dehydration and condensation of menthone with glycerol.
Substance Identification
| Synonyms | D,L-Menthone 1,2-glycerol ketal | SYMRISE FRESCOLAT MGA |
| CAS | 63187-91-7 |
| EINECS | 613-178-5 |
| FEMA | 3808 |
| HS.CODE | 293299 |
| Molecular Formula | C13H2403 |
| Moleclar Weight | 228.332 |
Application & Uses
- Menthone glycerol ketal is commonly applied in personal care products such as shampoos, shower gels, shaving products, toothpastes, mouthwashes, conditioners, body washes, soaps, lotions, creams, after-shave products, sunscreens, and antiperspirants.
- It serves as a cooling stabiliser for mint fragrances and is used in the formulation of daily chemicals, tobacco products, cooling fragrances, food & beverages (chewing gum, confectionery, chocolates, dairy products, baked goods, beverages, alcoholic drinks), and pharmaceuticals (topical analgesics, cough syrups, lozenges, nasal sprays, OTC medicines).
Features & Benefits
- Compared to menthyl lactate, menthone glycerol ketal delivers a milder cooling sensation whilst serving as both an immediate and long-lasting cooling agent. Non-irritating and menthol-free, it provides cooling effects akin to traditional menthol, with optimal pH range of 6-12 and easy incorporation as a colourless liquid that is non-irritating on cold skin application.
- As a sensory modulator, its weak minty odour preserves fragrance integrity while offering refreshing, long-lasting cooling (up to 25 minutes) suitable for broad applicability across personal care, food & beverages, pharmaceuticals, and consumer goods.
Sales Specification
| ITEM | VALUE | TEST METHOD & UNIT |
|---|---|---|
| Odor | A slight minty aroma that tastes almost non-existent but is accompanied by a lingering, pleasant cooling effect. | |
| Purity, Sum of isomers | 98 min | % |
| Absolute Density | 1.025 to 1.033 | @25°C, g/cm³ |
| Refractive Index | 1.4700 to 1.4780 | @20°C |
| Acid value | 1.0 max | mgKOH/g |
GHS Hazard Statements
| H-Code | H315/318/412 |
| P-Code | P263/280/302+352/305+315+338/332+313/337+313 |
| Response | R38/41/52/53 |
| Storage | |
| Disposal |
Storage
- Environmental & Temperature Control:
- Store in a cool, dry, well-ventilated area, and protect from light.
- Avoid high temperatures to maintain product stability and prevent decomposition or volatilisation.
- Keep in a cool, well-ventilated place.
- Container Management & Prevention:
- Ensure containers are tightly closed to prevent volatilisation and external contamination, and are clearly labelled.
- Ground all equipment containing the material to prevent static build-up.
- Hazard Isolation:
- Keep storage areas away from heat, sparks, open flames, and all sources of ignition.
- This combustible liquid should be stored in a separate safety storage cabinet or room.
- Keep away from incompatible materials to prevent hazardous reactions.
- Safe Handling & Inspection:
- Handle carefully, and stack stably.
- After prolonged storage, always check quality before use.
- Compliance & Emergency Preparedness:
- Strictly comply with all safety regulations, particularly those pertaining to combustible liquid storage.
- Ensure emergency plans are in place for unforeseen circumstances.
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