Terpene Phenolic Resin

Terpene Phenolic Resin (TPR) with high softening point and good stickability, particularly suitable to be used in making chloronorgutta rubber (graft polychloroprene rubber) adhesive for PVC artificial leathers. When once used, they can keep effective for much longer time as solvent adhesive because of their good quality of heat-resistance and better solvency for various kinds of flexible matter and resins.

TPR are also widely used in all kinds of solvent adhesive, dismodule type of CR adhesive, heat solvent adhesive, heat solvent adhesive stick & adhesive tape, and sole adhesive of high grade shoes.

Substance Identification

Synonyms
CAS 68648-57-7
EINECS N/A
FEMA N/A
HS.CODE 391110
Molecular Formula C16H22O
Molecular Weight 230.3453

Application & Uses

  • Adhesives
    • PSAs for medical, electronic and flexible packaging applications
  • Rubber Compounding
    • Partially replacing petroleum-derived tackifier resins in SSBR, BR and NR systems
    • Softening point and acid value comparable to industrial-grade phenolic resins; suitable for complex vulcanisation systems
# The above summary covers the latest applications of this product category (as of 2026); traditional applications are no longer displayed separately.

Features & Benefits

  • high softening point
  • good compatibility with many other resins
  • higher heat resistance
  • good adhesive for acrylic resin, natural rubber and synthetic rubber

Sales Specification

ITEM VALUE TEST METHOD & UNIT
Appearance Irregular-shaped solid cakes with yellow to light yellow colors
Acid Value 20 to 30 mgKOH/g
Colour 7 max @Gardner
Softening Point 140 to 160 @R&B, °C
ITEM VALUE TEST METHOD & UNIT
Appearance Irregular-shaped solid cakes with yellow to light yellow colors
Acid Value 1.0 mgKOH/g
Colour 7 max @Gardner
Softening Point 92 to 98 @R&B, °C

Q&A

How does the high‑softening‑point TPR145 terpene phenolic resin support graft chloroprene rubber (CR) adhesives used on PVC artificial leather?

TPR145 combines a high softening point of about 140–160 °C with an acid value of 20–30 mgKOH/g, indicating a phenolic‑modified terpene structure that provides both thermal stability and moderate polarity—two key requirements for graft CR adhesives used on PVC artificial leather. The phenolic polarity improves interaction with the chloroprene rubber matrix and enhances specific adhesion to plasticised PVC surfaces, where non‑polar hydrocarbon tackifiers often struggle to wet and anchor effectively. Its high softening point helps the adhesive film resist softening, creep and bond failure under the heat build‑up and bending loads that PVC artificial leather can experience in use, while still acting as an effective tackifier rather than an inert filler. In practice, TPR145 is typically used as the main tackifier in solvent‑based graft CR formulations for artificial leather and other flexible PVC applications, but formulators should still fine‑tune the tack‑to‑cohesion balance against their specific CR grade, plasticiser level and any co‑tackifiers in the system.

How can this terpene phenolic resin be used as a tackifier in SSBR, BR and NR rubber compounds for adhesive applications?

This terpene phenolic resin offers a high softening point (about 140–160 °C for TPR145) and a moderate acid value of 20–30 mgKOH/g, giving it phenolic polarity and thermal stability comparable to many industrial phenolic tackifiers used with SSBR, BR and NR. In rubber compounding, that polarity helps the resin interact with the rubber phase and with reinforcing fillers, so it can partially replace petroleum‑derived hydrocarbon tackifiers while improving green tack and filler wetting in solution‑SBR and BR‑based adhesive stocks. For natural‑rubber‑rich systems, the combination of terpene backbone and phenolic modification supports adhesion to a wider range of substrates and helps maintain tack under heat, which is useful in sole adhesives, rubber‑to‑fabric bonding and other solvent‑based rubber adhesives. Because Foreverest offers both a high‑softening, higher‑acid grade and a lower‑softening, low‑acid grade on this page, compounders can choose the more polar, higher‑softening version when heat resistance and cohesive strength are critical, or the lower‑acid, lower‑softening version where easier processing and softer compounds are preferred. Development teams should still run their own cure and performance tests, as the effect on vulcanisation and the final balance of tack, peel and dynamic properties will depend on the specific resin grade, rubber type and overall compound recipe.

Package

  • Paper Bag, 25kg net each, 12 months shelf life

Preview all the spec of packaging

GHS Hazard Statements

No GHS data available

Storage

  • guard against dust accumulation of this material
  • keep away from heat, sparks and open flame
  • keep containers closed when not in use

Remark

— Disclaimer —
The above information is believed to be accurate and represents the best explanation currently available to us. However, no liability is assumed for any consequences arising from the use of this content. The technical standards for our products are developed and updated jointly by our customers and ourselves; where any changes occur, the latest specification shall prevail and will be confirmed in the relevant contract.All suggestions and data provided are based on information we consider to be reliable and are offered in good faith, but without any guarantee, as the conditions and methods of use of our products are beyond our control. Foreverest® makes no warranties, whether express or implied, regarding the accuracy, completeness or suitability of this information, and expressly disclaims any implied warranty of fitness for a particular purpose. Prospective users should conduct their own tests and evaluations to determine the suitability of Foreverest® materials and any recommendations for their intended applications before adoption, and, where appropriate, should obtain confirmation or approval from the relevant regulatory authorities.Any references in this page to patents or patented technologies, including descriptive material derived from patents or citations of specific patent numbers, are provided for information only. They must not be interpreted as a recommendation to use our products in a manner that could infringe any third‑party patent, nor as a grant of any licence or permission to use patents owned by Foreverest®.

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