Terpene Phenolic Resin Emulsion

Foreverest™ Terpene Phenolic Resin Emulsion TPR602E is an aqueous, solvent-free dispersion of terpene phenolic resin, designed as a ready-to-use tackifier for water-based adhesive systems. With a solid content of ≥55%, an average particle size of 180 nm and a pH of 8–9, it is formulated for direct addition to acrylic, SBR and other synthetic or natural polymer latex systems. The terpene phenolic structure combines a non-polar terpene backbone — which promotes tack and surface wetting — with phenolic hydroxyl groups that enhance specific adhesion and cohesive strength, delivering high adhesion performance together with high shear resistance. Its solvent-free nature eliminates VOC concerns from adhesive manufacturing lines, while compliance with FDA 21 CFR 175.105 supports indirect food-contact adhesive applications.

Substance Identification

Synonyms DERMULSENE TR602 | Terpene phenolic dispersion | Rosin phenolic tackifier emulsion | Water-based tackifier resin
CAS 68648-57-7
EINECS N/A
FEMA N/A
HS.CODE N/A
Molecular Formula N/A
Molecular Weight N/A

Application & Uses

PSA Labels And Tapes.
  • PSA labels and tapes.
Contact And Industrial Adhesives
  • Contact adhesives for flexible substrates.
  • Packaging adhesives compliant with FDA 21 CFR 175.105.
Tackifier For Polymer Systems
  • Acrylic emulsion adhesives.
  • SBR latex compounds.
  • Synthetic or natural polymer blends.

Features & Benefits

  • Solvent-free — eliminates VOC concerns from adhesive manufacturing lines
  • ≥55% solid content — above typical industry levels, delivering more active tackifier per drum
  • 180 nm particle size — fine dispersion supporting uniform film formation
  • Ready-to-use pre-emulsified form — eliminates in-house emulsification, saving equipment and process development time
  • Excellent adhesion and cohesion — terpene backbone promotes tack and surface wetting; phenolic polarity provides specific adhesion and cohesive strength
  • pH 8–9 — compatible with acrylic, SBR and synthetic or natural polymer latex systems
  • Good mechanical stability — withstands moderate shear during mixing and coating operations
  • FDA 21 CFR 175.105 compliant — suitable for indirect food-contact adhesive applications
  • Six-month shelf life — storage stability supporting procurement flexibility

Sales Specification

ITEM VALUE TEST METHOD & UNIT
Brookfield Viscosity 800 to 1200 @20°C, 50 min-1, mPa.s
Solid Content 55 min %
PH 8 to 9 @20°C
Softening Point 95 to 105 @R&B, °C
Partical Size 180 nm

Q&A

When does it make sense for a formulator to use a pre‑emulsified terpene phenolic resin dispersion instead of emulsifying a solid resin in‑house for water‑based adhesives?

A pre‑emulsified terpene phenolic resin dispersion removes the need to melt and emulsify a solid tackifier on site, saving investment in emulsification equipment as well as the time and risk involved in optimising surfactant packages and process conditions. With a particle size around 180 nm and a narrow distribution, the tackifier is already dispersed at a scale that blends smoothly into acrylic, SBR and natural‑rubber latex systems without generating coarse droplets, grit or instability. Because the dispersion is solvent‑free, it does not add VOCs to the manufacturing line, which is increasingly important as coating operations move to fully water‑based processes and tighter emissions limits. The fixed softening point of the embedded terpene phenolic resin (about 95-105 °C) gives a predictable tackifier contribution to initial tack and peel, so batch‑to‑batch variation is more likely to come from the latex backbone than from in‑house emulsification variability, although formulators should still confirm compatibility and pH stability in their specific adhesive system.

How should warehouses and planners handle the 5-35 °C storage window and six‑month shelf life for this terpene phenolic resin emulsion?

Because this product is a water‑based colloidal emulsion, the 5-35 °C storage window is a hard operating limit: freezing drives the resin particles together and causes irreversible coagulation, while prolonged exposure above 35 °C accelerates water loss and coarse particle formation that can plug filters and coating equipment. The six‑month shelf life is generous for a tackifier dispersion but still much shorter than that of solid resins, so purchasing should plan deliveries in batches that will be consumed within this period rather than stockpiling as if it were a solid tackifier with essentially open‑ended stability. The instructions to keep drums tightly closed and to filter through 50 µm before use underline that this is a “living” dispersion whose particle size distribution will shift if water slowly evaporates from a partially used container, increasing the risk of grit and defects in the adhesive film. In practice, warehouse managers should verify that storage zones stay within the full 5-35 °C band throughout seasonal temperature swings, use FIFO (first‑in, first‑out) rotation, and avoid leaving open drums on the shop floor for extended periods to protect both stability and consistent application performance.

When switching between terpene phenolic resin emulsions, which key specification items should buyers check to ensure the new grade fits their established formulation window?

A solids content of at least 55% puts this emulsion at the high end of typical terpene phenolic dispersions - many similar products are in the 49-51% range - so it delivers more active tackifier and less water per drum, which affects both formulation balance and logistics. Its average particle size of about 180 nm is finer than the 200-500 nm ranges common in general‑purpose tackifier emulsions, supporting smooth film formation and stable blending with fine‑particle acrylic, SBR and natural‑rubber latex systems. The alkaline pH 8-9 range and Brookfield viscosity of roughly 800-1200 mPa·s indicate an anionic system designed for direct addition to common water‑based adhesive backbones without extra neutralisation or viscosity correction. Buyers moving from another terpene phenolic resin emulsion should therefore verify that solids, particle size and pH of the new grade fall within the formulation's established window, because differences in these three parameters alone can shift tack, shear and mixing behaviour even when the underlying resin chemistry looks similar on paper.

Can this terpene phenolic resin emulsion be added directly to acrylic or SBR latex, and what compatibility checks are recommended during formulation?

With a pH in the 8-9 range and an anionic character, this terpene phenolic resin emulsion is designed to be directly compatible with anionic or nonionic latex systems such as acrylic and SBR, so blending is generally straightforward and the risk of shock coagulation is low when it is added correctly. The fine particle size of around 180 nm and solids content of at least 55% mean the dispersed tackifier droplets are similar in scale to many PSA‑grade latex particles, which supports uniform film formation and a consistent tack profile across the coating width. Even so, formulators should always add the tackifier emulsion slowly into the latex under moderate agitation - rather than dumping it in all at once - to avoid local concentration spikes that can destabilise otherwise compatible dispersions. Before scale‑up, a small‑scale compatibility trial at the intended use level is recommended, monitoring for excessive viscosity increase, grit or coagulum formation, and pH drift over 24 hours, since the specific acrylic or SBR grade and its stabiliser package will ultimately determine long‑term blend stability and performance.

How does the terpene phenolic resin structure allow this emulsion to deliver both high adhesion and high shear performance in a single tackifier?

Combining a non‑polar terpene backbone with phenolic hydroxyl groups, this resin structure provides the dual character that allows the emulsion to deliver both high adhesion and high shear resistance: the terpene segment promotes tack and surface wetting, while the phenolic polarity improves specific adhesion to more polar substrates and contributes to cohesive strength within the adhesive film. A softening point of about 95-105 °C for the base resin places it in a range that balances strong initial grab with enough film integrity to resist creep under sustained load, which is important for pressure‑sensitive labels and tapes that must hold during converting and end use. Because the tackifier is already dispersed at around 180 nm in a solvent‑free aqueous matrix, it can be added directly to acrylic or SBR latex without solvent flash‑off or high‑temperature processing, helping preserve latex mechanical stability while still building tack and shear. Formulators should still verify the tack‑to‑shear balance at their intended loading level, since the optimum ratio depends on the elastomer solids content, coat weight and any co‑tackifiers used alongside the terpene phenolic dispersion.

Package

  • Plastic Drum, 200kg net each

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GHS Hazard Statements

No GHS data available

Storage

  • The best Stored temperature at 5-35°C (41~95°F)
  • Keep from freezing
  • To prevent evaporation and subsequent formation of coarse particle, keep containers or drums closed.
  • Shelf life: 6 months
  • filter: 50um

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Remark

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The above information is believed to be accurate and represents the best explanation currently available to us. However, no liability is assumed for any consequences arising from the use of this content. The technical standards for our products are developed and updated jointly by our customers and ourselves; where any changes occur, the latest specification shall prevail and will be confirmed in the relevant contract.All suggestions and data provided are based on information we consider to be reliable and are offered in good faith, but without any guarantee, as the conditions and methods of use of our products are beyond our control. Foreverest® makes no warranties, whether express or implied, regarding the accuracy, completeness or suitability of this information, and expressly disclaims any implied warranty of fitness for a particular purpose. Prospective users should conduct their own tests and evaluations to determine the suitability of Foreverest® materials and any recommendations for their intended applications before adoption, and, where appropriate, should obtain confirmation or approval from the relevant regulatory authorities.Any references in this page to patents or patented technologies, including descriptive material derived from patents or citations of specific patent numbers, are provided for information only. They must not be interpreted as a recommendation to use our products in a manner that could infringe any third‑party patent, nor as a grant of any licence or permission to use patents owned by Foreverest®.

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